As I wrote IR laser diode by itself should have lover Vf (about 2V not 5V).
Looks like you are talking about whole IR laser module (diode + lens + driver in metal housing).
Input voltage will depend on particular module requirement.
OdicForce specifies "Design voltage: 5V". No way to tell if it can handle 6V (4 fresh alkaline under light load)
They sell whole 200mW IR laser and say that it can be used with 2 CR2 3V batteries or 1 LiIon.
If you have the same module you are good and also you should be able to use 4 NiMH.
Again, it depends on driver used in module. Try to get information from manufacturer.