H2 storage for long haul transport?
There have been so many miracle 'solid' hydrogen schemes announced for decades now that I'm extremely skeptical of all such claims.
The primary problem is that of density. Hydrogen is the lightest element, thus anything you bind it to will outmass it - generally by at least an order of magnitude. Thus the net hydrogen content ends up being a tiny fraction of the solid containment medium and whatever convenience you gain by not having to deal with compressed hydrogen at 5000 - 10,000 PSI (350 - 700 bar) you lose its hydrocarbon-like energy density. And much to my surprise they actually mention the mass fraction:
How does it fare in terms of density by volume and weight? Chen tells us the powder can store a hydrogen weight percentage of around 6.5%. "Every one gram of material will store about 0.065 grams of hydrogen," he says.
So storing hydrogen - with 33.33kWh of thermal energy per kg - in this format means your actual density gets cut down to 2.16kWH/kg. And that's before getting into the yield after separating it from the storage medium
(it takes nontrivial heat to free the hydrogen from the powder). Compressed hydrogen does better and I note that they're comparing the 5000 PSI / 350 bar standard that was common in vehicular demonstrators ~20 years ago vs the 10,000 PSI / 700 bar standard that's in place today
(i.e. on vehicles you can buy/lease such as the Honda Clarity, Hyundai Nexo). Also unknown is how rapidly the hydrogen can be extracted from the medium - something that compressed hydrogen doesn't have an issue with.
The article makes a lot of reference to cryogenic processes which as best I can tell aren't being used outside of space exploration and some early experiments in the aviation sector. Cryogenic hydrogen is a problem a as fuel because it's not
storable - in order to benefit from the lighter tanks than compressed hydrogen demands it must either be refrigerated (or superinsulated) to prevent it from heating up and boiling, consumed/offloaded before it heats up, or
vented as it heats up - the latter two being troublesome for vehicles that are parked for any length of time. Otherwise, I gather the petroleum sector makes hydrogen via steam reformation of hydrocarbons - a process that refineries can perform with existing plant equipment - rather than the baffling "cryogenic distillation process" they take pains to compare their invention to on the production side.