Info on Lithium Batteries

Glenn

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Jan 11, 2002
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Here is a quote from an article on Lithuim batteries:

Flat discharge curve. The terminal voltage of a lithium battery is very stable. The battery is able to maintain a relatively constant terminal voltage until the last 15% of its life for significant discharge rates. At lower discharge rates the terminal voltage will stay almost constant until the last 5% of the battery's life.

This is in direct contrast to alkaline batteries where the terminal voltage starts a rapid drop from the very beginning as the internal battery resistance climbs, wasting much of the remaining power at high discharge rates.

Low internal resistance. A lithium battery employs a wound plate construction to provide a large plate surface area. This allows the battery to operate with a very low internal resistance and produce very large currents.

The low internal resistance in a lithium battery is maintained throughout its life, rising steeply just as the battery is dying. This is why the voltage curve is so flat and why the lithium battery is so efficient.

Wide temperature operating range: -60° to 80°C (-76° to 176°F). The lithium/sulfur dioxide chemistry is very tolerant of wide temperature ranges. Most other battery chemistries don't work very well below freezing and they also die in short order at elevated temperatures.

At -40°C (-40°F) the battery retains about 50% of its capacity when providing 0.5A, 65% of its capacity when providing 0.1A and 85% of its capacity when providing 0.01A.

Lithium batteries can take the summer southwest desert heat and still provide years of service.

Conventional alkaline batteries fail when the temperature drops below freezing. This makes them inappropriate for cold weather operations. Their shelf life is also dramatically reduced when exposed to high temperatures (alkaline batteries left in the glove compartment in the desert southwest sometimes don't make it through the entire summer).

10-year battery shelf life. Lithium batteries can be stored at room temperature for 10 years and still retain 70% of their rated capacity. The shelf life is reduced to 5 years at significantly elevated temperatures. If you are using lithium batteries to power emergency equipment, we recommend you test the equipment regularly and replace the lithium batteries at least every 5 years. The batteries removed from the emergency equipment can be used for less critical functions so their remaining capacity is not wasted.

The lithium/sulfur dioxide battery chemistry has an interesting characteristic you should know about. When a battery has been stored at elevated temperatures or for an extended period of time, a passive layer forms over the lithium anode. This layer contributes to the long shelf life of the battery. When the battery is placed in service, this layer dissipates quickly but may temporarily depress the battery terminal voltage.

Like all batteries, lithium batteries should be stored individually packaged. Care should be taken to avoid excessively high temperatures (80°C or 176°F), shorting the batteries or physically damaging the batteries.
 
Hello Glenn,

Thanks for the information. People have gone to using lithium batteries in the car flashlights to insure that they will work after being exposed to extreme temperatures. It is good to realize that the 10 year shelf life is rated at room temperature.

Tom
 
I think there are 3 different chemistries for non-rechargable lithiums. The Energizer L91 is Lithium/Iron Disulfide. The Cr123a's from everready and Duracell appear to be Lithium/Manganese Dioxide. The Lithium/Manganese Dioxide is (I think) an older technology.


The Lithium/Iron Disulfide will provide an amazing amount of current. It's 2900 mah capacity is measured at 200ma drain.


Daniel
 
Yep, Lithium have excellent mid/high current drain performance compared to Alkalines.

I ran a comparison test with one of my uFlex drivers using 4 Lithium and 4 Alkalines. Both tests were driving 380mA into a Q2H luxeon. uFlex is a down converter so it was probably pulling roughly 200mA from the batteries during the test.

First graph is with the 4 Alkaline AA's:

runtime.gif


And then with 4 Eveready Lithiums (note, the initial drop was probably faster - I got called away after starting the test and didn't get the next sample point until 20mins or so had passed):

runli.gif


The results speak for themselves - notice the flat discharge curve of the Lithiums. Great batteries for certain applications - spendy though /ubbthreads/images/graemlins/frown.gif

george.
 
There are about 30 different chemistries for Li cells, I did have them all listed in a manuscript.
I have at least 5 of them at home.
 
Spacemarine: no, it is not. It is the manual for the electrical power source lecture for people studying technical chemistry (pretty different from normal chemistry). It is about 300 pages of primary, secondary and fuel cells.
 
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