LEAST corrosive battery chemistry???

Sub_Umbra

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The subject only refers to rechargeable chemistries for
AA, AAA, C and D cells.

Okay. All cells will leak under the right (or wrong) circumstances.

Will they all do the same amount of damage to a given light if they
happen to leak?

Will one chemistry do less damage if a cell leaks?

Will one chemistry do the same amount of damage faster or slower
than another type if there is a leaker?

Another way to put it: What is the safest rechargeable chemistry to
use in your favorite light(s)?

Any input will be appreciated.
 
Well, we can take SLA off of the list that's for sure. I'm not sure if there is SLA in the form of aa/c/d etc though. I'm not sure what the pH of the checmicals in NiCAD/NiMH are, but NiMH has less toxic heavy metals but of course that still doesn't answer your question. I'm thinking that they are neutral perhaps???? Not sure... Interesteing...
 
AGM batteries are lead-acid but quite leak-resistant. The electrolyte is totally absorbed in thin sheets of material. No corrosive gases are generated. I recall reading of demonstration where someone fired a bullet through one and it just kept on working with no spilled electrolyte.

The original spec for the Miata was an AGM battery, which was remarkably small and well-suited to its placement in the enclosed space of the trunk. That battery lasted me 7 years. There are also smaller ones made for other uses, such as alarm systems, etc. I used 6-volt versions in bicycle lights. Both the car battery and my smaller ones were made by Panasonic. The 6v, 4.5 AH version was within the realm of flashlight size; there are smaller ones also.

http://panasonic.com/industrial/battery/oem/chem/seal/index.html


Their drawback is weight. Even though they are lighter than conventional SLAs due to reduced volume of electrolyte, they're still fairly heavy compared to other rechargeables.
 
I tend to think in terms of everyday battery types that NiCd are proably about the least corrosive - NiMH I have no experience with though. Never had any trouble with damage done by the few leaky NiCd's I've encountered though.
 
I saw a leaky NiCAD today in a motorola walkie talkie. It had blue/white crystals corroded looking all over one contact.

So It's got something caustic in it.
 
[ QUOTE ]
IsaacHayes said:
I saw a leaky NiCAD today in a motorola walkie talkie. It had blue/white crystals corroded looking all over one contact.

So It's got something caustic in it.

[/ QUOTE ]

I've read on other threads that NiCad 'juice' is very corrosive stuff, but blessedly, I have no experience with leaky NiCads.

Has anyone out there had a NiMH leak in a light?

How corrosive was the mess?
 
Is someone up for an experiment?
All you would need are some expendible batteries, some metal pieces (preferably spring steel, copper and plated copper), a hack saw and a digital camera.

I wish someone had asked this a few months ago before I started grad school and I had the time to do this kind of stuff.
 

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