Slight 'swelling' on 9500mAH D NiMHs

Sub_Umbra

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Slight \'swelling\' on 9500mAH D NiMHs

I just noticed a slight swelling of the normally flat negative terminal of some of my 9500 mAH Powerizer D cells. I noticed this on one cell this morning and when I inspected the rest of them I saw that the negative terminal has become slightly dome shaped in four out of the fourteen cells I'm using.

Some details:

1--Sixteen cells were bought from BatterySpace ~eleven months ago. They were purchased to use as two six cell sets for my CD boom-box, two cells for my late model EL Hyper-Blaster, and two spares. All of the 'domed' terminals have occurred on the cells in the two six cell sets I rotate through the boom-box. I have a third six cell set from a different manufacturer that is part of the boom-box rotation -- they're all ok. Because there are three sets, each boom-box set gets recharged about once every 25 days. The Hyper-Blaster set only gets recharged ~half that much.

2--I'm using an AccuManager 20 for all of my charging. I rotate three sets for the boom-box because a six cell set actually takes over 2 days to charge in the four station AC2020. It has worked out quite well as it also keeps me reasonably stocked with D cells for blackouts -- I don't have to tap into the alkaline stash unless things get pretty serious.

3--I'm happy with the performance I've gotten from these cells so far and since I'm the only one who has ever handled them I can state with certainty that none of them have been dropped, etc.

I normally check the voltage of the cells before and after charging with a DMM but mine died last week. As soon as I post this I'm going to go out and get another. I haven't noticed anything odd in the readings so far.

Sooo, anyone have any idea what's going on here? Anyone seen this before? How concerned should I be? Are these cells heading towards catastrophic failure? Is this something I can live with as long as the cells will still physically fit into the device and charger?

Any help will be appreciated.

/blinks, scratches head
 
Re: Slight \'swelling\' on 9500mAH D NiMHs

sounds like a pressure increase.
Bubbles (so to speak)
what Rate of charge are they rated for, and what rate are you charging them?
what is the rate at the END of the charge cycle?
 
Re: Slight \'swelling\' on 9500mAH D NiMHs

hmm now i think we know what the Voltage drop is (that the chargers read to terminate) and why it indicates the end of the charge /ubbthreads/images/graemlins/smile.gif eeeek.
 
Re: Slight \'swelling\' on 9500mAH D NiMHs

While I don't know the exact charge rating of the cells, note that it does take well over 24 hrs to charge a 9500 mAH NiMH D cell with the AC 2020. That would not seem to be in the catagory of a 'quick charger', which is more in line with where I would expect damage to cells from charging too fast, if that's what you meant.

IIRC the Ansmann uses a 1AH charge rate for D cells compared to 700 mAH for the AccuManager. I also have one set of six 9000 mAH NiMH Ds from CCrane that are much older and show none of the doming from being charged in the same charger.
 
Re: Slight \'swelling\' on 9500mAH D NiMHs

the bulging is gas buildup due to overcharging or bad design.
quality on cheap chinese batteries is hit or miss.
i would use the bulging cells in something that you wont be upset over if they leak.
mark them and see if others start bulging.
 
Re: Slight \'swelling\' on 9500mAH D NiMHs

[ QUOTE ]
Sub_Umbra said:
While I don't know the exact charge rating of the cells, note that it does take well over 24 hrs to charge a 9500 mAH NiMH D cell with the AC 2020. That would not seem to be in the catagory of a 'quick charger', which is more in line with where I would expect damage to cells from charging too fast, if that's what you meant.



[/ QUOTE ]

yup that is what i meant, also its important to collect the INFO from users, so I (at least) know what kills something, so a bit of a question, and a lot of learning.

at that rate, it should be able to overcharge for a week /ubbthreads/images/graemlins/smile.gif without damaging the cells, to bad that dont look like the situataion.

the large capacity ni-mhy D cells that i have have a RATE listed that SEEMS very low for the capacity of the cell, although (again) it would guarentee that an overcharge wouldnt go over C.1 or 1/10th the capacity of the cell.

meaning it seems like the low rate they listed, would insure the cell even if it was overcharged.
 
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