Strange observation charging RCR123 with WF-139

Xe54

Enlightened
Joined
Sep 12, 2005
Messages
201
Greetings:

I charged an AW RCR123 on a UF WF-139 charger using a spacer, and monitoring the cell voltage while connected to the charger with a multimeter.

When the green light came on, the cell voltage was 4.67V . Immediately upon removing the cell from the charger, the cell voltage was 4.16V .

The open circuit voltage from the charger is 4.96V .

I suspect what is actually happening is that the cell's protection circuit is opening the circuit to the charger before the charger senses that the cell is fully charged. This might be due to the tolerances on the protection circuit being a bit low. I don't observe this behavior with AW 18650 cells (which I can't recall what voltage they terminate at).

However, if this idea were true, then I might expect to measure the open circuit voltage of the charger across the cell. OTOH, the protection circuit might be drawing some current from the charger, slightly reducing the voltage, but not letting the cell receive the current.

I don't believe the cell is getting overcharged because the voltage is actually modest at 4.16V when I take it out. If it was over a safe voltage when taken out then I would be greatly concerned.

Has this been observed by anyone else? Ideas?
 
FYI:
Protected AW RCR123s have a high voltage cut-off at 4.35V. This is how high the charging voltage goes on a WF-139 when charging these cells...

The jury is still out on whether or not this charging method is as safe as the proper CC/CV method. My gut tells me it's probably not ideal, however, I have read a few studies online suggesting that with most modern LiCo and LiPo cells, real danger doesn't kick in till well over 4.4V cell voltage, with tolerance for charging voltage that exceeds 4.25V (during charging) that has minimal impact.

-Eric
 
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