Hi tonygamble,
What I am trying to find out whether they are actually that mah
Very likely a huge exaggeration, the NP-F9xxx has 6 cells, 2 sets in series of 3 cells parallel in each set. They use typical 18650 Li-ion cells, which is usually 2400-2600mAh, 3x brings this to 7200-7800mAh. Any such battery that claims higher mAh than these figures it is either a big lie or a very expensive pack with even higher quality cells.
I have several dropping into 7.1 to 7.5. Presumably you would you say they are close to EOL but please bear in mind they are almost brand new in my case? When one is paying between £25 and £45 a cell you can't be throwing them away too soon.
I assume you mean £25 and £45 a NP-F pack, not cell? Yours are probably fake mAh numbers simply because the total cost 25-45 pounds is very low to have those higher capacity 3000+mAh cells required. Additionally, the need to lie about mAh also brings another issue, the actual quality of the cells used. Quite often they use stripped batteries from laptop power packs or anyway binned batteries, which are old and aged and have quite elevated impedance and self discharge. I had two such cheap NP-F batteries, brand new and bad out of the box which was simply unreliable for any use. On the other hand, there are relatively "cheap" brands of good quality. I have a yongnuo NP-F750 which states 5200mAh (so presumably it uses 2600mAh cells), I can't comment if it is actually 5200 but it keeps powering my LEDs for 3+ hours when my bigger "noname" NP-F9x struggle to reach that, a couple don't even reach 3 hours. Also, this good battery was charged to 8.3V a week ago and right now it reads 8.28V. If yours read 7.2V or so after a full charge, they are damaged/toasted inside or simply they have those inferior quality cells with rapid self discharge hugely demonstrated, basically they are EOL. Still if they serve you well, no need to toss them but I highly doubt they are of good quality or have that high capacity. My experience with all those quite cheaper brands: they don't worth it, there are a bit more expensive brands which are good, yongnuo is a good one so far for me.
What do you think will happen when my Godox LED
I don't know the behavior of this particular led you have. I mostly use Yongnuo YNIII, this has its cut-off point quite low, less than 6V under load, this gets to the dangerous area to trip the protection circuit or damage cells as per the answer below. Fortunately, Yongnuo has a "power left" indicator which is voltage based, so when it reaches the lowest value 1, it is close to 6.3V and it is time to change the battery. At this point, the brightness is noticably lower too. The bottom line is you shouldn't try and drain down completely these packs, it is bad. Try to do a real test with the voltimeter/wire with your pack on the LED to measure the running time/voltage.
I don't suppose for me it matters when I am using a pair in a Godox LED
It matters for the health of each NP-F pack, regardless if you use 2 NP-F to run the light. If it gets unbalanced, some cells in the pack will struggle more compared to other cells in there, may get their voltage below safety values whilst the overall voltage remains higher because other stronger cells keep it up. This isn't good really. Unfortunately, I don't see a way to balance NP-F packs.
I got the iMax B6 from a friend, due to the proprietary terminals on NP-F it is virtually impossible to connect the charger directly with the provided clips. I don't know if there is some dedicated pins to use with this charger on NP-F, if anyone knows please inform us. I did use screwdriver bits to make the connection, not the safest or the best approach but it did seem to charge/discharge. Tomorrow I'll try to make a full charge/discharge cycle to better judge if this justify the trouble. So far, it looks cumbersome to use hobby chargers for NP-F batteries but may worth it for capacity measurement. For normal charging, I believe specific NP-F chargers serve this best.