Have to define "pure white", there isn't such a thing with white phosphor LEDs. Basically he'll need to define a color temperature that he's happy with, and find a suitable LED to match (pure white, in the sunlight sense, is of course a blend of all colors (to some degree), a white LED puts out a specific frequency pattern (kind of a double-hump, one tall, one short, the tall being the "white phosphor" optimized frequencies, the other being the blue LED "base" emitting frequency leaking through), and will be lacking at one end or the other unlike the "flat" frequency of daylight.
Best bet would actually be multiple RGB LEDs arrayed and blended to create the whiteness desired, much more closely approximating sunlight, but tough to mix thoroughly to avoid "rainbow shadows" etc, especially in a portable unit.
The other problem is what is the application? I think most photography lights tend to start around 25 watt halogens at the bottom of the chart (really 35W+ seems "low"), and go up from there... to match that would take a LOT of LEDs (hundreds of 5mm, or maybe 10-20 or more of the new Crees, in a carefully shaped or diffused fixture), a "ring" of 5MM leds can't do it, period unless it's several feet around. If he wants just a flash, a few lux/cree units at high amps can probably do a decent job, but not for more than a few milliseconds at a time in any reasonable fixture.
Now if he wants a "micro-photography" light, that's reasonable, I'm no expert in tints but seems the Nichia CS is commonly said to be very "white" in color. It still won't be "daylight" white though, as described above.