OK, time to continue my thesis. Nothing much new here today except a bunch of people yakking about brand A vs. brand B (same old, same old).
In my previous post I tried to explain why I think 'white' LEDs are so glaring and annoying to dark adapted eyes. It's primarily because of the blue spike in the spectrum, and the relatively weak greens.
Time for some more graphs. Here's the output of a 'full-spectrum' lamp from
fullspectrumsolutions:
Of course, this is anything but 'full spectrum'. It's another multi-phosphor light. However it does provide a good approximation of sunlight to most people. Notice where most of the spectral energy is in this graph. Yes, it's in the green and red parts of the spectrum. Actually the three spikes in the graph roughly correspond to the peak sensitivity of the (blue, green, red) cones. Notice how the green and the red spikes are weighted much more heavily than the blue. Again, since over 95% of the cone cells in the eye are senstive to green and red (~530nm and ~575nm peaks) these radiation bands are most important for detecting contrast and for strain free reading. In a way this is taking the spectral output of a sun like source and 'sampling' it at the three regions corresponding to the three cone cells 'peaks' in the eye.
Below is a graph from venderbilt showing the spectrum of some common light sources (
link).
The top graph is a blue LED + quantum dots, the second from top graph are the typical curves for a 'white' LED (blue LED + phosphor/scintillator). Notice how both of these have a 'notch' in the green part of the spectrum. Very bad, those wavelengths are important. If anything you want a peak in this part of the spectrum.
So, what to do? It's frustrating because in may ways white LEDs are closer to a true full spectrum source than just about anything out there. It just needs a little work. One obvious solution would be some sort of filter to attenuate the blue spike in the spectrum caused by the LED. The drawback would be slightly lower efficiency, and the need to tweak the phosphor to maintain the white balance. This might result in a more pleasing light. There's also the question of boosting the notch in the green part of the spectrum. Not certain how this could be done.
So it's tricky. It's possible to create a good approximation of white by mixing different colored LEDs... but the overall efficiency is not as good.
The efficiency of LEDs has finally surpassed most fluorescents (though perhaps not as good as high wattage incandescents - HPS and halide lights). The spectral output still needs tweaking though.