"A mixture of acetylene and air becomes thus explosive (will explode if a light is applied to it) when only 3.35 per cent. of the mixture is acetylene .... while, on the contrary, if air is added to acetylene, the mixture becomes explosive as soon as the acetylene has fallen to 52.3 per cent. Hence the immense importance of taking precautions to avoid, on the one hand, the escape of acetylene into the air of a room, and, on the other hand, the admixture of air with the acetylene in any vessel containing it or any pipe through which it passes.
The danger is, however, materially increased, especially with acetylene installations for illuminating purposes, as they are generally delivered under the most impressive assurances that there can be no danger whatever, and under that impression the apparatus is left, for daily manipulation, in the hands of persons who are entirely ignorant of the dangerous nature of the gas and the construction of the apparatus, and being more or less used to the easy handling of the ordinary gas, cannot or will not understand restrictions, but in case of the apparatus getting out of order, in their own self-confidence, and with the best intentions, take steps to put it in order, which may have serious results.
It is easy to forget that by placing the acetylene apparatus in the house a more or less dangerous result may always be expected, so also by careless and unskilled manipulation of the plant, or by natural wear and tear, or by corrosion or rust, which scarcely can be avoided, or by using inferior material in order to lower cost of production, all of which will sooner or later produce leakage, and cause an explosion ..."
http://chestofbooks.com/crafts/metal/Welding-Cutting/Chapter-IX-Acetylene-Welding-Accidents.html
Kind of reminds me of lithium-ion rechargeable batteries, in a way.