Want more understanding of internal resistance

InHisName

Enlightened
Joined
Apr 29, 2009
Messages
213
Location
Warminster, PA
Many folks have referred to internal resistance being a key factor in battery cell condition etc, that I purchased a PLDaniels IRM v005R2 from: http://nqrc.com.

This measures internal resistance 3 ways: 1 ohm load, 0.5 ohm load, and 0.5 ohm load 50% duty cycle. See his web site for pdf manual for further details. I have bought 16 AAA NexCell precharged 7 months ago. I just bought 16 Duraloops 3.5 months ago. I cycled each cell twice then did a full break-in at 800Mah to measure capacity.

The NexCells came in at 775, 25 above the 'minimum' capacity. The irm measurement for these cells typically came to
1.43_________1.19_______1.08
155-209____175-222___170-216 milli-ohms
0.5/50%_____1.0ohm____0.5ohm test load

I have been using the cells in a FRS radio (walkie talkie) and every 2-3 days it says batteries need charging. I remove them and recharge them in my C9000. All 'seemed' to go well until I tried them in a high current need device, ran down in very short while! Worked great 7 months ago, though!

New irm measurements are:
1.44__________1.00________.83
225___________229________780

Looks like these things are loosing their abilities. Still great in the radio though.

So to compare to my Duraloops (in use similar radio for 3.5 months) and got the following measurements:
In Sept 09:
1.42-146____1.03-1.18______1.02-0.82
67____________74__________329-460

Just now:
1.42___________1.02_________0.84
158____________114_________609

These were charged very 3 days / 90 days for 30 cycles
The MAH hours put 'in' was usually 800-850 MAH so they weren't fully discharged.

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So folks are there 'tricks' to partially restore cells back to near original health ? If the resistance gets near or over 1,000 milli ohms the C9000 says "HIGH" and refuses to charge older cells.

I am experimenting by discharging a really weaker cell at 1,067 mo via a flashlight bulb until 'dead' then recharge on my MHC204F which doesn't 'care' about the 'high'. I'll do it 3x cycles and then test the internal resistance to see if there is any difference.
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Any engineer types care to comment with formulas explainations etc ?
 

TakeTheActive

Enlightened
Joined
Dec 16, 2008
Messages
830
Location
Central NJ, USA
Many folks have referred to internal resistance being a key factor in battery cell condition etc, that I purchased a PLDaniels IRM v005R2 from: http://nqrc.com.

...Just now:
1.42___________1.02_________0.84
158____________114_________609

=====

So folks are there 'tricks' to partially restore cells back to near original health ?
Suggestions:

For posting data, consider using CODE tags (instead of underscores) for improved readability.

Just now:
Code:
1.42           1.02         0.84
 158            114          609
LABELs as to what the numbers represent are also appreciated. ;)

For *CRAP* cells, CLICK on my Green Sig Line LINK and read about Cell Recovery.
 

InHisName

Enlightened
Joined
Apr 29, 2009
Messages
213
Location
Warminster, PA
Just what factors affect internal resistance ?
Others have said:

  • overcharging
  • overheating (big overcharge)
  • venting of moisture
  • sitting 24/7 in charging cradles ?
  • memory effects ?
  • what else ?
For 3 cells, wiith the low drain usage I have had & charging with C9000, I don't think I have an venting issue. Nor memory, as I have cycled & break-in a few times but not much change. 8 other cells were in charging cradle for 2.5 years. So maybe for them.
 
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