I'm going to be controversial here and contradict the previous two posts.
The TK75's battery carrier uses 2S2P configuration which gives the 8.4V working voltage. If you add a second you still have 8.4V as the second carrier is also 2S2P, and is connected in parallel by the TK75's contact design.
Now the effect of this is that combined the cells are get 2S4P (remember that the total number of cells for XSYP = X x Y, so 2S2P has 2x2 or 4 cells and 2S4P has 2x4 or 8 cells).
The reason for talking about this is to reinforce the most important principles when combining cells.
If using cells in series, it is very important that they are as well matched as possible in capacity, charge level and that they are protected.
However, when using cells in parallel, this capacity matching is far far less important. In fact the only really important factor when using cells in parallel is matching the charge level. (Note that cell age can affect its ability to hold full charge, so cells should be similar in age - and age refers not just to calendar age, but to cycles as well).
When you have cells working in parallel (or even batteries - being a collection of cells), each individual cell will work together with the others, and if one cell is weaker, the others will simply work a bit harder. All the cells are linked in voltage, so it will be the strongest cell that works hardest. If you have one 2600mAh cell with one 3400mAh cell connected in parallel, during use, the 3400mAh cell would normally maintain its voltage better than the 2600mAh cell, but when working in parallel, as the load causes the voltage of the two cells to drop, the stronger cell will take the load off the weaker one but the cell voltages will stay the same.
So take this to the TK75's configuration...
The TK75 can run on 2 cells as long as you install these in 2S1P configuration (one cell with +ve facing towards the LED and one towards the tailcap). These cells are one 2S1P 'battery' and need to be closely matched.
Theoretically, you could now use 2 matched cells of a different capacity to make up the second 'P' part (to make it 2S2P), however it is far easier to avoid mistakes, by using a set of 4 matched cells in the TK75's battery carrier.
That is one battery carrier, so when moving onto a second one (which will be connected in parallel), the theory of using cells in parallel comes into effect. So if you have a second set of 4 matched cells that you can keep together in the second battery carrier, this will then be working in parallel with the first battery carrier so the actual cell capacity is not important, only the level of charge matters.
So despite the overstated paranoia regarding li-ions on CPF, given a bit of logical thought, I personally would be happy to use the cells as you described with 4x2600mAh in one carrier and 4x3400mAh cells in the second. I am happy to do this ONLY because they are used in parallel, if the combination of battery carriers was in series, I would not consider this safe.
Before doing this I would ensure all cells are charged to the same state of charge (measure the resting voltage of the fully charge cells), and each set is kept together and never mixed between the carriers.
Yes, ideally, in an ideal world, and one in which money is no object then get 8 new matching cells, but in the real world where money is a consideration, as long as you think about what you are doing, you don't need to buy 8 new cells, the four you are thinking of will be fine if used as I have described.