Unless the two surfaces have been polished like glass smooth, and prefectly flat, always use thermal grease, or thermal epoxy. It can increase heat transfer significantly. I would recommend Artic Silver epoxy, or Devcon 2 hour setting epoxy mixed with Artic Silver paste.
I've got several lights that run Luxeons in the 700ma range without any heat problems; they propably don't even reach 110F after an hour of operation.