FYI, a lot of copper wire covered in Teflon is usually coated with silver. Teflon 'attacks' copper.
Something to take note of using silver is that it is stiffer and springier than copper. It can be difficult to use in tight places as it can put a stress on a solder joint that doesn't have a secondary mechanical hold. It wants to be the shape that it wants to be and to rely on just the weld joint can put a stress on said joint. It not that it can't be overcome, it just needs to be noted.
...and cost vs copper of course.
Lots of advantages over copper in heat tolerances, conductivity, anti-oxidation, it adheres more easily/better than copper.
I would use silver plated vs gold plated copper and get the same results in most common uses. Any advantages of "gold plated" copper can be met by using silver plating...and as mentioned most teflon coated copper is already silver plated.