This seems odd... C9000 anomaly?

SilverFox

Flashaholic
Joined
Jan 19, 2003
Messages
12,449
Location
Bellingham WA
CPF member Bones sent me a couple of Eneloop cells to check out. One of them is a dud, and has been a dud since originally purchased. I have a few tricks up my sleeve, but this seems to be a bad cell. The problem is that it has higher internal resistance, which results in capacities in the 1650 - 1700 mAh range. This puts it in the well worn category, but not in the "crap" category.

At any rate, I have been running cycles and Break-In's on these two cells in the C9000. Normally I don't leave cells in the charger, but rather than writing down the value from the good cell, I just left it in the charger, discharged, and would compare the results back and forth with the problem cell.

About a week later... I noticed that the voltage of the discharged cell was increasing...

I decided to run a test on this.

I charged both cells up and let them top off overnight. I then ran a discharge at 100 mA. The good cell came in at 2016 mAh, and the problem cell came in at 1625 mAh. This is interesting because it seems that this cells capacity is falling off rapidly. About 10 cycles ago the problem cells capacity was over 1650 mAh.

I left the cells in the charger, discharged, for a few (I think it was 3 or 4) days. At this time the voltage had increased to 1.30 volts. I then ran another discharge at 100 mA and recorded 180 mAh from the good cell and 153 mAh from the problem cell.

Normally, when you discharge at a low rate there is very little capacity observed during a second discharge. I would have expected less than 10 mAh. To further test this, I removed the cells from the charger and let them sit for 24 hours. I then ran another discharge and recorded 10 mAh from the good cell and 0 mAh from the problem cell.

I have two C9000 chargers, and these results were observed on my oldest unit. I happen to be breaking in some GP2700 mAh cells for testing on my other unit, so I decided to see what happened with them.

After the Break-In cycle, I discharged them, then charged them at 1500 mAh. I only let them top off for a short period of time (about 1 hour I think), then discharged them at 500 mA. Capacities were 2331, 2336, 2368, 2360 mAh. I left them in the discharged condition for 2 days, and then repeated the 500 mA discharge. During this time the cell voltages recovered to 1.25 volts. Capacities this time were 81, 61, 70, and 74 mAh.

Next I charged the cells and once again discharged them at 500 mA. When they finished the discharge I removed them from the charger and let them sit for 24 hours. I then discharged them again at 500 mA and capacities were 17, 14, 13, and 18 mAh. This time the cell voltage only recovered to 1.18 volts.

Given the higher discharge rate, and the higher capacity cells, this last observation seems more normal to me. The question is Why does leaving the cells in the charger result in almost 5X more capacity...?

Does the C9000 switch into trickle charge mode after discharging...?

Tom
 
Last edited:
That's an interesting observation. If I had my shop set back up I'd stick an O-scope on it to see what's happening in such a situation. If you have an O-scope or even a DMM I'd check put it across the battery while it's in the charger to see if it appears to be still getting a charge if that's possible. Check it in the charger and then pull it out and compare to see if there is a difference in voltage and current in versus out of the charger? If all else fails ask Silverfox - he's the expert :D
 
Hello Matrixshaman,

Yes, I guess I will have to look a little further into this...

This is a condition that I would never have run across in "normal" use, but I found it rather interesting.

Tom
 
I might take a guess that the early C9000s applied the low rate maintenance charge whenever they were in the idle state and all other activities had finished, including discharging. And maybe newer units have corrected this anomaly?
 
I've noticed this type of thing previously myself.

On one occasion, I put a cell that had fully self discharged in to do a discharge on the C9000 - as expected, the C9000 gave a result of 0 mAh. After leaving the cell in the charger for a while, I found that the voltage had climbed up from somewhere around 1.00 volts up to around 1.20 volts.

I've also seen other times where it has done this, but the above is the best example that shows that the C9000 is definitely doing some sort of charging after doing a discharge...
 
Interesting observations.

When I am doing testing, I'll set the cells to discharge overnight and then I take them out in the morning.

The cells would normally have about 3 hours relaxation time in the charger after they have been discharged.

I've never really paid much attention to the voltage figure and haven't attempted the 100 mA discharge.

I have a group of cells that are due for their maintenance charges soon....I'll have to try this and see what happens.

BTW, my C9000 is a 0G0KA.
 
Hello Alfreddajero,

You can follow what I did as outlined in the first post, or try something else.

I wonder if this happens when a cell is rejected due to high internal resistance too...? This may offer a way to charge "crap" cells and get a little more use from them...

Tom
 
I wonder if this happens when a cell is rejected due to high internal resistance too...? This may offer a way to charge "crap" cells and get a little more use from them...
I've got a bunch of NiCd cells from our solar lights that none of my chargers will charge, not even the 22-hour timed dumb charger.

I'll try that when my C9000 is freed up.
 
Okay i might just figure out a way to do it.......but usually if i have a cell thats crapped out on me i just throw it in the recycle bin. Please just call me Al.........
 
I've got a bunch of NiCd cells from our solar lights that none of my chargers will charge, not even the 22-hour timed dumb charger...
If a FIXED CURRENT, TIMED 'dumb' charger (i.e. 'Forming Charge') won't charge your old, worn NiCD cells, I doubt that a 'Trickle Charge' from the C9000 will have any effect either.

What current is your 'dumb' charger?
 
How can one test this on there C9000, both of mine are OHOBA........
The theory being proposed is that the C9000 supplies the "10mA Maintenance Charging Current" whenever it is idle.

So:
  1. Insert 1-4 cells and DISCHARGE them at 100mA
  2. When the DISCHARGE function is complete, LEAVE them in the C9000 for one week
  3. After one week, unplug/plug in the C9000 and after it boots, select DISCHARGE at 100mA
  4. Post the results of the SECOND DISCHARGE
 
There's another anomaly with the C9000 that I don't recall seeing posted on the forums here:

When charging a pair of cells that have been used together - i.e. both should require the same amount of charge, about 90% of the time, the cell that is inserted into the right hand slot shows a measured 3-5% extra charge being given to it.

An example of this would be if the 2 cells are inserted into slots 1 & 2, and the first slot shows a charge of 1000 mAh, the second slot would often end with a charge of between 1030 mAh and 1050 mAh. This also occurs with slots 3 & 4.

This happens with all cells that I use the C9000 to charge.

So far I haven't been able to work out a satisfactory explanation. Not that it really matters too much, but it is strange nonetheless...
 
The theory being proposed is that the C9000 supplies the "10mA Maintenance Charging Current" whenever it is idle.


So:
  1. Insert 1-4 cells and DISCHARGE them at 100mA
  2. When the DISCHARGE function is complete, LEAVE them in the C9000 for one week
  3. After one week, unplug/plug in the C9000 and after it boots, select DISCHARGE at 100mA
  4. Post the results of the SECOND DISCHARGE


I will give it a try.......
 
I've noticed this type of thing previously myself.

On one occasion, I put a cell that had fully self discharged in to do a discharge on the C9000 - as expected, the C9000 gave a result of 0 mAh. After leaving the cell in the charger for a while, I found that the voltage had climbed up from somewhere around 1.00 volts up to around 1.20 volts.

I've also seen other times where it has done this, but the above is the best example that shows that the C9000 is definitely doing some sort of charging after doing a discharge...

That is just the nature of the cells. They would do that even out of the charger.
 
Hello Jhellwig,

I agree that the voltage will recover with time, but this does not equate to an increase in capacity.

I put some Eneloop cells that I had beat up doing 15 minute charge testing on in the C9000 and selected discharge. These cells had been sitting for a few months, and showed voltages of 1.15 and 0.95 volts. They are now showing voltages of 1.24 and 1.22 volts.

Tom
 
cool thanks for the weird stuff

i believe in two probabilities here, one you would have to repeat the FIRST incident to determine.

1) After the Break-In cycle, I discharged them, then charged them at 1500 mAh. I only let them top off for a short period of time (about 1 hour I think), then discharged them at 500 mA. Capacities were 2331, 2336, 2368, 2360 mAh. I left them in the discharged condition for 2 days, and then repeated the 500 mA discharge. During this time the cell voltages recovered to 1.25 volts. Capacities this time were 81, 61, 70, and 74 mAh.

2) Next I charged the cells and once again discharged them at 500 mA. When they finished the discharge I removed them from the charger and let them sit for 24 hours. I then discharged them again at 500 mA and capacities were 17, 14, 13, and 18 mAh. This time the cell voltage only recovered to 1.18 volts.

so right after you discovered 2, you would have to do 1 AGAIN, to see if its just how the chemicals reacted after being cycled there.
( that which doesnt recover discharged :)

but THIS
I noticed that the voltage of the discharged cell was increasing...
initial discovery, which led you to the wondering and testing, seems to indicate that it WAS the charger, but again we have a cell that "has chemicals that are not converting totally" and no "complete" discharge, because the discharge is to a specific point using a specific style.

the other probability that i have often wondered about:
Reducing any parasitic effects of charge curcuit

--------redundant noise here-----------
How do they keep from discharging a battery THROUGH the chargers curcuitry, there is always some pico draw between the connection poles possible, no mater what kind of electronic tricks you put in them, electronics have tiny "leakback" paths that can draw tiny bits of power, unless you get a full mechanical disconnect.
SO
some slower chargers have simple very lightweight topping/trickle, so a battery can stay on the charger and it doesnt get discharged (which attempts to address self-dicharge too obvioulsy).
MABEY
to solution the problem of the teeney tiny draw through the chargers curcuit stuff, they put a teeny tiny charge into the curcuit, without the intent of charging or changing anything, but just to keep things even.
--------------------------------------

I suspected the first thing , not the second, because they couldnt solution a parasitic draw if the power was off, and i doubt they get that complex at <$100.
although
after seeing your numbers , sure its 5 TIMES, but it isnt even a percent of anything is it ? its a few milliamps here and those few miliamps are relative to the ammount recovered when the voltage was sagging (and then not) at the low end. discharge was never "complete" only ever to a specific cut-off point. the repeated discharge after time is also not "complete" its just picking up a few electrons off the bottom of the barrel :) a barrel that is not Empty.
 
Last edited:
Top