Well, based on my limited knowledge, this is what I would see as the most obvious problem. I'd assume that the 2 x nimh would run out of power before the lithium. If that were the case I don't suppose it would be a big deal, you'd easily see that the output of the light was way down, and you would then (presumably) replace the lithium and charge the 2 x nimh. However, and this where I think it might get ugly. What if you make a mistake, like for example putting back the same partially used lithium with 2 new nimh, or if you just have a lithium that you think is new and fresh but has self discharged for whatever reason? You could get to a point where the 2 x nimh start to charge the lithium, or at least attempt to.
If that did happen you still might be fine as by then the output would be low enough to be obvious (based on it working on just 2 x nimh at that point), but what if you don't notice, what if you leave it on, what if.... whatever. Like I said, I'm no expert but I just can't see how mixing battery chemistries can be anything other than "unadvisable" at the very least. If Silverfox ever writes down his years of knowledge and gets published (I'd buy that book! :paypal:), I'm sure that chapter one, page one will be "don't mix battery chemistry". What would be on page two, his explanation, well, maybe he'll see this and chime in :)