Yes, series increases voltage, parallel keeps it the same.
Former keeps Ah capacity the same, latter increases it.
Just know that usually "12V" means a midpoint at least that high, many load devices will cut out before 11V.
You should not charge LI cells past 4.1V if you want good longevity, and even at over 90% SoC, under load most will be well below 3.7V.
3.65V is a normal midpoint but only measuring **at rest**