Another Eneloops Incident - update to Magic Maha Mojo

matrixshaman

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Update in Post #15
After trying to switch on a Midland weather radio that had been sitting for some time I remembered it doesn't really have an off switch - it stays on all the time. Unfortunately I had put two AA Eneloops in it and it apparently ran them down. I was concerned how low they went and got out the voltmeter. One tested about 0.5 volts and the other one tested 2.4 millivolts! I retested that one a half dozen times to make sure I had that right and that it wasn't just a loose connection or something but it was clearly reading barely over 2 millivolts or .0024 volts! If I recall correctly from some of our battery experts here that's not a real good thing for Eneloops although probably not as bad as it would be for Li-Ion chemistry. BUT I got out the Maha C9000 to see what I could do to save this battery. I put it on the Maha and saw it pop up first at 0.04 volts. Normally the first reading I see when putting any NiMH in the Maha is around 1.62 volts as I believe the Maha tries to make sure you are not putting in an Alkaline or other type that it does not want to charge. But this time it popped up at 0.04 volts so that on one hand confirmed my voltmeter reading that this had almost no power left in it and on the other hand it told me the Maha does something different with an almost dead battery. I watched for a few more seconds and the second reading to come around was 1.37 volts. That was after only about 5 seconds of being on the charger. I then removed the battery and checked it on the voltmeter. It now read 1.34 volts after only being on the Maha for about 5 seconds!
Does this mean the Eneloops have some sort of built in protection circuit like some of the Lithium Ion rechargeables? Or could it have popped up that fast in those few seconds - in voltage at least? From my experience I don't think a battery could come back that fast in that short of time even in the voltage reading. I've put Nicads and similar small batteries across a 10 Amp battery charger to shock them back to life and none came back that fast that I recall even at 10 amps and 12 volts (yes I used protective gear when doing this - welders helmet, gloves etc.).
I had the charge rate set to 1000ma on the Maha. Any ideas as to what I have observed here? Magic Maha Mojo?
 
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Re: Fascinating Observation about Eneloops - built in PTC or Magic Maha Mojo?

Hello Matrixshaman,

With a good quality cell in reasonable condition it really doesn't take much to get it up to, or over, 1.2 volts.

You should mark those cells. The damage to them will depend on how long they were kept at voltages under 1.0 volts.

Do you feel lucky?

Tom
 
Re: Fascinating Observation about Eneloops - built in PTC or Magic Maha Mojo?

IIRC they were probably sitting in the weather radio 2 weeks or so and I think that radio normally kills of alkalines in about 2 or 3 days. This is the first time I put Eneloops in this radio. I won't do that again unless I'm on a road trip and watching the radio. I guess I had expected that once the radio didn't have enough voltage to operate that it would not draw any more current - wrong guess :shakehead
 
Re: Fascinating Observation about Eneloops - built in PTC or Magic Maha Mojo?

If you look at the typical discharge curve of an NiMH cell, the slope of voltage/charge becomes almost vertical right at the end. The recharge curve is very similar in shape, so a tiny addition of charge is enough to shoot the voltage right up again.

On the other hand, what use is a critical piece of equipment like a weather radio that you can't turn off? Isn't it then guaranteed to contain drained cells when you need it to work? I'm puzzled.
 
Re: Fascinating Observation about Eneloops - built in PTC or Magic Maha Mojo?

Mr Happy;On the other hand, what use is a critical piece of equipment like a weather radio that you can't turn off? Isn't it then guaranteed to contain drained cells when you need it to work? I'm puzzled.
A turned off weather alert radio is totally useless. These radios are meant to be plugged in 24/7 with the batteries only kicking in during a power failure.
 
Re: Fascinating Observation about Eneloops - built in PTC or Magic Maha Mojo?

Oh, I see. The batteries are for emergency backup. (I was thinking the time you would want such a radio is when you are far from civilization like a cabin in the mountains, where there is no mains supply.)
 
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Re: Fascinating Observation about Eneloops - built in PTC or Magic Maha Mojo?

I've got 3 weather radio's - one Midland plugs into 120 vac and has battery backup, one from Oregon Scientific runs well for a couple weeks at least and then there is that Midland portable which for some reason kills batteries in a very short time. It does have an input for a wall wort but I didn't bother finding that.
I have seen some batteries pop back fairly quick but I was really surprised as I had just put it in the Maha, saw the .04 volts and watched it for the next cycle to see the voltage - like all of a few seconds and seeing it jump that high seemed rather amazing :faint:
Not sure if that's a big cheers for Maha or Eneloops or both but it looks like it has come back to life again.

It's running in the 'Analyze and charge' mode now (been running since my first post) and it's reading 2009 mah on the cell that was at 2.4 millivolts and 2028 mah on the cell that had hit 0.5 volts while in the 'Rest state'. IIRC that is higher than I've ever seen them at. I ran all of them through the Analyze and charge function when I first got them and most were a bit under 2000 mah - some in the 1800's and some 1900's but I don't think any were over 2000. I think these had 2006 dating when I got them if that makes any difference.
 
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Re: Fascinating Observation about Eneloops - built in PTC or Magic Maha Mojo?

That's interesting. Apparently a good way to perk up NiCd cells is to short them out with a bulb right down to 0 V before charging, but this is not recommended for NiMH cells. I wonder if somehow Eneloops handle that better?
 
Re: Fascinating Observation about Eneloops - built in PTC or Magic Maha Mojo?

Hello Matrixshaman,

Keep in mind that the first thing to fail on the Eneloop cells is the low self discharge rate.

I have some "aged" Eneloop cells that are testing in the 1700 and 1800 mAh, but if you leave them sit for around 10 days, they fully self discharge.

Tom
 
Re: Fascinating Observation about Eneloops - built in PTC or Magic Maha Mojo?

to SilverFox --


Were your "aged Eneloops" simply "aged", or

were they "abused" also ?


Normal usage ? Or "Rough usage" ?


Approximately how many cycles did they endure,
to reach this point ?



Thank you for all of your help, input, and advice. :twothumbs

_
 
Re: Fascinating Observation about Eneloops - built in PTC or Magic Maha Mojo?

SilverFox - Actually I had noticed a couple Eneloops seem to be losing voltage fairly fast while others do not. I promise I'm going to be more careful with these. I don't want to become one of those people talked about in your sig line ;)

Happy - I think the weather radio that tortures these batteries may be why they have been marked down to $9 at WalMart - or I believe this is the same one from our CPFM 'Good deals' section :
http://www.cpfmarketplace.com/mp/showthread.php?t=175970
 
Re: Fascinating Observation about Eneloops - built in PTC or Magic Maha Mojo?

Hello Matrixshaman,

I have some "aged" Eneloop cells that are testing in the 1700 and 1800 mAh, but if you leave them sit for around 10 days, they fully self discharge.

Tom

Hiya Tom,
WHAAAA ? hey start a new thread on this :) i wanted to know about this since the first day they came out.
whats it doing hiding in here :)
that is the one thing about enloops that i wont find out for TIME, what the heck happens to them, and will they STILL be Magic Low self discharge , when the warrenty runs out :)
 
Re: Fascinating Observation about Eneloops - built in PTC or Magic Maha Mojo?

Hello Burgess and VidPro,

The cells came from Handlobraesing. He says they had around 50 cycles on them when he sent them to me. They now have more than double that... :)

When I got them, they were pretty much dead. I have been "nursing" them back to life. It has been a real challenge. I figured that if I ever got them back to decent shape, I would then start a thread on the process.

I have been using them to test out the various charge algorithms used in the C9000, the BC-900, the Schulze, and the Eneloop chargers.

They are still above 80% in capacity, so they aren't totally "crap," however they seem to have lost their low self discharge characteristics.

I am not sure what Handlobraesing was using for a charger, but the cells were acting as if they had been on trickle charge for an extended period of time. Voltage depression, to the extreme. I did a normal discharge on them at 500 mA and got around 3 mAh from them. Tried to charge them and was constantly plagued with getting a "High" reading on the C9000. I then ran a discharge on the CBA and found that they had "normal" capacity in the 0.9 - 0.5 volt range. I think I got around 1600 mAh from my first discharge, but as you can see, the voltage stinks.

As you can see, it is a work in progress. I am not sure if I can revive the low self discharge rate characteristic, but they are now performing relatively well at a 500 mA discharge.

While I don't know their actual history, I would say that they were abused, in some way, that they more than likely saw "normal" to "rough" usage, and were considered dead. I believe Handlobraesing was using a 2 hour charger, but I am not certain of the trickle charge rate. I would have to look back on his posts to see what he was actually using. I believe he also has a 15 minute charger, so they may have seen a few cycles on that as well.

If I ever get them back into decent shape, I will start a thread on them, but for now, it's simply a work in progress...

Tom
 
Re: Fascinating Observation about Eneloops - built in PTC or Magic Maha Mojo?

I have to correct myself on a previous post above. I'm still learning how to use the Maha charger. The capacity I mentioned above over 2000ma is not correct. I think that is how much it had put in at that point but this morning it shows capacity as 1877 ma on the cell that had been down to 2 millivolts and 1923 on the one that had been down to 0.5 volts. It actually says 'capacity' now on the display. These numbers sound about like what I had been getting on these before the rundown.
 
Re: Fascinating Observation about Eneloops - built in PTC or Magic Maha Mojo?

A bit more interesting Maha Mojo and an update due to another 'Incident' :ohgeez: I had some Eneloops in a transceiver I use often but after using it one day the radio was conspicuously missing. We've got backups so I didn't look too hard at the time. A couple weeks later it turned up in a chair under a cushion and was still turned on but quite dead. I pulled the Eneloops and found a couple reading only 4 to 5 millivolts while one still had about 0.8 volts on it. I put them in the Maha C9000 and started a refresh and analyze cycle on each of them. It got interrupted by power going down about 80-90% of the way through so I started it again. When all were done the stated capacity of at least 2 were over 2000 Mah - one was 2032 Mah, one 2043 Mah and about 1.44 to 1.45 volts - the third I forgot to check and pulled it when I saw 'Done' - it was the first done so I'd expect it had a good capacity too. Thanks again to Maha for providing a great charger like this. I know that as SilverFox has said they may lose some of their LSD due to this abuse but at least they are still useable batteries for most purposes and it seems they actually now have better capacity than they did before IIRC.
 
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Sorry to be slightly off topic guys,
SilverFox, since you seem like someone who has a lot of experience with restoring and testing. I have a question for you:
I have a huge pile of thrown away batteries, some of them are probably 10-20 years old. I've been trying to revive them with mixed success.
I noticed that some cells, can be discharged second time at lower current.
For example, some cell was charged @ 700ma, and discherged @ 500. It showed 430mah. Right after discharge is done, I set another discharge action (without charging them) but this time current is 100ma, And i pull another 500ma out of them.
Does it mean that such battery is only suitable for low-current applications?
Does it do any good to discharge it @ low current?
What would you do with such batteries.

Thank you.
 
junglemike - SilverFox is a good one to ask this of but you might want to PM him on that as I'm not sure he'll check in here on this older thread. I'd hazard a guess for you but I'm sure it wouldn't be as good as his advice. I can only suggest that if you have a Maha C9000 to run the breakin cycle on them if the analyze cycle doesn't seem to bring them up to par.
 
Hello Junglemike,

A couple of the reasons cells go bad include large crystal growth and increased internal resistance.

Sometimes the capacity of the cell is still available, but at a lower voltage. However, most battery operated products require a minimum voltage to operate.

If your poor performance is due to crystal growth, you can sometimes break up the crystals by slow discharging.

If your poor performance is due to increased internal resistance, a lower current will keep the voltage from dropping as much and you may be able to get some additional use from it.

However, keep in mind that crap cells are still crap cells. Some may be less crappy than others, but they are still crap.

If a cell doesn't come up to at least 80% of its initial capacity after spending some time trying to rejuvenate it, recycle it.

You will have a much more rewarding and enjoyable experience with rechargeable batteries, if you take the time to weed out the crap cells and get rid of them.

Tom
 
Re: Fascinating Observation about Eneloops - built in PTC or Magic Maha Mojo?

Hello Matrixshaman,

Keep in mind that the first thing to fail on the Eneloop cells is the low self discharge rate.

I have some "aged" Eneloop cells that are testing in the 1700 and 1800 mAh, but if you leave them sit for around 10 days, they fully self discharge.

Tom

Fully self discharge in 10 days? Uh oh, sounds like the dreaded sanyo high self discharge problem. None of my nimh cells completely discharge within 10 days so far except a bunch of sanyo 2500mah, and this includes cells 1600mah quest gold cells from whenever those were released. This is especially bad considering they are LSD cells.

I hope it's more a cycle problem than age. I use my LSD cell lightly and charge them infrequently. I hope that after 2-3 years they don't just go kaput!
 
I'm looking more in details the "loss of low self-discharge" ability in LSD cells.

It still too early to say - since I still have to take some microphotography of the "injured" cell internals.
I can only say how I induced the problem to the cell: by continued overcharge.

It seems from a preliminary analysis that the modified BA5 (the negative electrode) as soon is "scratched" only superficially, it will let H2 out, so the cell is no longer an LSD. The negative electrode in Ni-MH cells, other than store H2 mulecules during the charge process and releasing them during the discharge process, also act as a catalist to reform water at the end of charge. This last operation (unnecessary in Ni-CD cells) kills it.
At this point in time, I would say that "any" overcharge will kill an LSD cell.

*A Word about charging Series-Parallel combinations of LSD Cells*

I was able to destroy involuntarily some LSD cells in a 5S3P arrangement, due to unproper voltage termination. -dv/dt methods doesn't work well in Series-parallel setup of cells, if at all.
I developed a methodology to use 90% of the capacity of LSD cells in Series-Parallel configuration since the -dv/dt kills them.
I charge the SP combo with constant current of 0.05 C (i.e. 100 mA for a 2000 mA/h cell) until it gets to 1.45 V / cell, than cutoff. In this way the cell is charged at 90% capacity, which is the capacity it is going to store for long time.
The trick is to avoid any temperature increase during the charge process, so the 1.45 V mark is a good indicator of charge termination.
My 5S3P pack of Uniross Hybrio cells in my modified Black&Decker spotlight has gone now 100 cycles and is still going strong. Last self discharge measurement was a loss of 1% capacity in 2 months.

Regards

Anthony
 
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