I`ll try...
Energy is the ability to do work, often measured in Watts.
when we discus Watts in terms of electricity, it`s made up of Volts times Amps, so a 4 Amp 4 Volt battery will deliver 16 watts (Volts X Amps = Watts).
so your battery will be able to run a 16 Watt radio for 1 hour, or a 32W radio for half an hour, or 64W for 15 mins etc... there is a limit to this however! you can`t carry on doubling it forever (except on paper) because the battery chemistry and physics forbid you from drawing Infinite watts in Zero seconds! LOL
I`ll let someone else deal with capacity because it`s a bit vague in this context.
edited to add: it works the other way as well, you could run an 8W radio for 2 hours, a 4W for 4 hours etc...