Welcome to the wonderful world of electronics! Like someone else suggested, there are some web sites where you can get yourself an introduction to Ohm's Law and the relationship between current and voltage. Check out your local bookstore, too. But then, watch out! Diodes are semiconductors, and they don't play by the rules. They cheat. The relationship between voltage and current in a normal resistive load are completely linear - apply twice the voltage to a resistor, and twice the current flows. But with an LED, or most any other semiconductor for that matter, the relationship is very non-linear: depending on what part of the LED's current/voltage curve you're on, a very small increase in voltage will result in a huge increase in current. Check out the specs given for LED's and you'll see that non-linear curve. But take heart; the information is out there, and it's fun learning. Enjoy!