How to care for AW's rechargeables?

SAVAGESAM

Newly Enlightened
Joined
Nov 27, 2007
Messages
197
Location
Fresno,CA.
Ok first off thanks again for everyones advice. I purchased (4) protected 17500's and a charger from AW and The plan is to set these up as two sets, set "A" and set "B". I use my flashlight everyday but only for short (5-10 minute) periods. How often should I cycle these sets through the charger in order to get maximum life out of them? How much should I drain them before charging them again? Any questions I didn't ask that I should of? Thanks in advance.
 
Hello SAVAGESAM,

If you limit your discharge to around 80% of the cells total capacity you should get good cycle life from your cells.

You will have to determine the details of this through testing. You can start with a run time test. Next multiply that by 80% and divide that by your 10 minutes per day usage. This will give you the number of days between charging.

Tom
 
in addition to what Silverfox said, try to avoid discharging the cells until the protection circuit turns off the light. In my limited experience, most difficulties with the RCR123, 10440, 14500, and 18650 cells that I have had started with discharging the cells too low. If the light starts flickering, turn off the light and change cells.
 
Hello SAVAGESAM,

If you limit your discharge to around 80% of the cells total capacity you should get good cycle life from your cells.

You will have to determine the details of this through testing. You can start with a run time test. Next multiply that by 80% and divide that by your 10 minutes per day usage. This will give you the number of days between charging.

Tom

What voltage does it translate to? The cells come precharged at 4.0V.
I charged with the Pila charged and they cut off at 4.2V.

Does that mean they are 80% discharged at 3.3V? Or close to it?
 
Hello Etc,

The cut off voltage is related to the current load on the cell.

The best way to determine 80% discharged is to do a run time to empty, then multiply that time by 80%. Once you have done this you can them measure the voltage to figure out what it is.

Tom
 
Hello Juggernaut,

Since the nominal voltage of a Li-Ion cell is 3.7 volts, you are not getting much run time out of your cells. You may want to change and recharge when then drop to 3.5 volts.

Since there is no issue with voltage depression or "memory effect" with Li-Ion chemistry, there is no problem charging when they get to 4.0 volts. Just keep in mind that you are only using around 20% of the cells total capacity.

Tom
 
Hello SAVAGESAM,

I would say that running them to a low voltage is harder on the cells...

However, I did read a study of cell phone use where husband and wife combination's were studied. The wife's batteries lasted longer than the husbands. When exploring why, they discovered that the wife tended to run the phone until the battery was nearly completely discharged, while the husband tended to charge the battery after very little use. The battery manufacturer concluded that the husbands battery died because it spent most of its life fully charged, and at that time, a fully charged Li-Ion cells was not stable.

This gets back to storing Li-Ion cells at 40% full. Studies were done showing that a cell that was stored at 100% full deteriorated quickly. Since the husband basically kept his battery at, or near, 100%, they figured that was the cause of the early failure. The usage of the wife on the other hand, had the battery more like 50%.

Since that study was done, the battery manufacturers have added stabilizers to the electrolyte used in Li-Ion cells, and now we have cells that are lasting longer than 1 - 3 years.

I am not sure if this is still an issue to be concerned with, but it is worth considering. The other thing the cell phone manufacturers did was to limit the charge on the cell phone battery. They found that charging to 4.2 volts gave around 400 - 500 charge/discharge cycles where charging to 4.1 volts gave around 1500 charge/discharge cycles. The down side is a loss of around 10% of the cells capacity.

Tom
 
Every few days I check the voltage on the cells I am using in various flashlights, and check the cell in my wife's flashlight. If the voltage is under ~3.95V open circuit, I tend to go ahead and charge it up.

If it were up to me, I would always charge cells before they dropped below ~3.7V open circuit, but that doesn't always happen.
 
I am not sure if this is still an issue to be concerned with, but it is worth considering. The other thing the cell phone manufacturers did was to limit the charge on the cell phone battery. They found that charging to 4.2 volts gave around 400 - 500 charge/discharge cycles where charging to 4.1 volts gave around 1500 charge/discharge cycles. The down side is a loss of around 10% of the cells capacity.

Tom

I charge AW's protected 18500 with the Pila charger. It charges to 4.2V and then cuts off.
How can I stop the charging process when I get to 4.1? Is there an easy way, other than taking them out every so often and checking the voltage?
 
Hello Etc,

The Pila IBC charger is set to charge to 4.2 volts. For charging to 4.1 volts I use my Schulze. It has settings for both 4.1 and 4.2 volts.

Tom
 
Thanks for the tips and keep them coming please. I thought I remember reading a while back about not using your batteries right after they come off the charger? Something about waiting one day to let the voltage drop a bit???
 
I have a question along these lines. It was never worth it's own thread, so here will do nicely.

I often see people mentioning "pull them off the charger when they reach xx volts", but how do you do that? I am in the habit of fully charging, then using a light to drain them a little, check cells after they have rested, drain some more, repeat, then get them resting at 4.1v that way.

Can I touch the + and - ends of the battery with my multimeter while it is still being charged?

I saw something in a thread a while back that implied I could, but I've never really been sure.
 
Hello Juggernaut,

Since the nominal voltage of a Li-Ion cell is 3.7 volts, you are not getting much run time out of your cells. You may want to change and recharge when then drop to 3.5 volts.

Just keep in mind that you are only using around 20% of the cells total capacity.

Tom

Oh I know. I just like having it ready for when ever I really need it:twothumbs. That's about how much I use every two days around the house.

Thanks for the help;).
 
I have a question along these lines. It was never worth it's own thread, so here will do nicely.

I often see people mentioning "pull them off the charger when they reach xx volts", but how do you do that? I.


I have the Pila Li-Ion charger, supposedly the better "cheap" charger.
Apparently there is no easy way to do it. It just stops at 4.2V.

I cannot justify a Schulze charger now...

I will try timing charging AW cells with Pila, e.g. the cell is at 3.5V and it should take 2 hours to charge to 4.1V (as an example, I don't know the exact charge time).

Problem is, the cell will be discharged to various capacities, sometimes 3.5, sometimes 3.8V, whatever. So there is no constant time.

Maybe there is a formula you can come up, say charging every 0.1V takes xx minutes.
I am afraid however it's not a linear equation so probably wouldn't work very well.
 
Thanks for the tips and keep them coming please. I thought I remember reading a while back about not using your batteries right after they come off the charger? Something about waiting one day to let the voltage drop a bit???

This only really applies to situations where you are using a battery chemistry that has a tendency to have some voltage settling after charging, IN CONJUNCTION with a direct drive bulb setup that is pushing the bulb to the limit anyways. Resting cells, especially NiCD and NiMH cells, will reduce the likelihood of burning out that bulb prematurely. I have personally observed a voltage settling tendency in my collection of 10 Emoli 18650 size LiMn chemistry cells. After ~24 hours they tend to settle to ~4.10V, another few days and they settle to ~4.08V. I have tested their runtime into various loads and they are performing as they should be, so the cells are in decent condition. As a result of my observation of this voltage settling tendency, I have made the suggestion to users of LiMn cells who are planning to drive something like an MN21, to let the cells rest to reduce the chance of blowing that expensive bulb...

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niconical said:
I have a question along these lines. It was never worth it's own thread, so here will do nicely.

I often see people mentioning "pull them off the charger when they reach xx volts", but how do you do that? I am in the habit of fully charging, then using a light to drain them a little, check cells after they have rested, drain some more, repeat, then get them resting at 4.1v that way.

Can I touch the + and - ends of the battery with my multimeter while it is still being charged?

I saw something in a thread a while back that implied I could, but I've never really been sure.

I use my DSD more often than not, it actually has the contact pins for the cells "exposed" from the top, so I very frequently just take the probes from the multimeter and put them right on those pins on the charger to see what the charging voltage is at. Keep in mind that the actual cell voltage will almost always be at least a few hundredths lower than the charging voltage, depending on cell size and charge rate and what charging phase it's in. Small cells charged fast, like an RCR123 in a Pila IBC, will have a charge voltage of probably 0.1V higher than the actual voltage of the cell through the Constant Current phase of the charging. A larger cell, like say, an 18650, on a slower charger like the DSD, will only be like maybe 0.03V lower than the charge voltage... It will take some experimenting, but you can get a feel for when to pull them by testing on the charger, seeing what voltage it is at, then just go ahead and yank the cell to see where it's really at, then resume charging is you want to... On the Pila charger, since you actually have a Constant Voltage phase, once the charging voltage reaches 4.20V, it will just hold it there, and the current flowing into the cell will taper off as the actual cell voltage tries to find equilibrium with the 4.20V of the charger.

I find myself checking charge-voltage mostly just to keep mental track of how much longer before I need to come back and check on them again. I will usually pull cells when they are over 4.15V charging voltage if I catch them in time. The very end of the DSDs charging algorithm brings em to about 4.22V, after which point they usually fall to ~4.10-4.16V depending on the size of the cell and how new it is.... so that's plenty acceptable to me.

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etc said:
I will try timing charging AW cells with Pila, e.g. the cell is at 3.5V and it should take 2 hours to charge to 4.1V (as an example, I don't know the exact charge time).

Problem is, the cell will be discharged to various capacities, sometimes 3.5, sometimes 3.8V, whatever. So there is no constant time.

Maybe there is a formula you can come up, say charging every 0.1V takes xx minutes.
I am afraid however it's not a linear equation so probably wouldn't work very well.

You're right, it's not perfectly linear, and there probably isn't any perfect way to setup a timer to prevent a full charge. Best way to do it is to get a feel for charging time, check cell voltage during the charge from time to time, and yank them before the charger has a chance to top em up all the way manually. Or get a more expensive charger...

In theory, one could probably set up a pretty simple circuit that would cause a voltage drop to the cell, such that the charger would terminate normally, but the resulting cell voltage would be a little lower. Maybe one of the Electrical Engineers on here could tell you how to do that. I doubt it's hard. Probably just a certain type of diode would do the trick.

Eric
 
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