Maybe a dumb question. If you want high Vf, why not add another diode in series with a lower Vf luxeon. A schottky will increase the effective Vf bin by about 1 1/2 letters and a regular Si diode by about 3 letters. BTW, using a lower Vf luxeon and a series resistor will give you a flatter discharge curve [current level over the total discharge of the cells] than using a higher Vf luxeon without resistor. IMHO, direct drive from low impedence cells like NiCd, NiMh, LiMnO2, Li-ion is a bad idea.