A single cell AAA or sub-AAA cell does not have a lot of capacity. That generally means you'll notice the dimming. The dimming will be noticeable while in use rather than between uses. Recharge when you notice the dimming. QTC lights can be a little tricky because you might attribute the dimming to the QTC and not the cell. I've made this mistake and slightly crushed the cell button top. (I twisted the light, it didn't get brighter and I took the cell out and charged it. Put it back in and the light was bright again.)
I was busy during the week and didn't put gas in my car. I want to go for a spin in the mountains. I can take a chance and go and hope I have enough gas. I can be cautious and stop and buy gas. Or I can look at the gas gauge. I don't see the drama. A simple volt meter for li-ion batteries can be useful because the voltage gives an indication of remaining capacity. A more complicated meter that measures voltage under load is needed for other chemistries.
Leave the scientific theories to brain surgeons and astrophysics. Chemistry and consumer electronics are based on observations. Compared to charging li-ion cells after a they are completely drained (2.5 V), topping off will increase their useful life (the number of times you recharge/cycle them). This is best practice based on use and not some complicated, convoluted theory. Battery University has some interesting information.
Two cell applications require a little more care because the cells need be balanced. This is true for li-ions, lithium primary CR123 especially, but is true for other battery chemistries. Again, no drama, no theory - just best practice based on observations.