I'll start with a little background on emergency lighting as practiced in the US at this time, just so we're all starting off on the same page:*
You have two basic types of system, central and distributed. Distributed means that you have boxes scattered around your facility, each box has an AC connection, it trickle charges a battery, if that box loses power it turns on a light and runs it off the battery. Each box is fully independent.
The advantage of distributed is that it's cheap to install. You don't have to hire electricians to spend days crawling around running wires in the walls and ceiling. You can start small and build as fast or slow as you like. If one unit dies a replacement is not that expensive. The disadvantage of distributed is maintenance. You are supposed to test and monitor these things and with a distributed system someone has to walk all over the property with a ladder and test each unit one at a time.
Central means that you have a closet somewhere with a pile of big batteries. When you lose power to that closet the batteries start feeding power to wires that run to lamps scattered all over the building. They all come on. With a central system you test one board, measure one set of batteries, activate it, stroll once around the facility to see that all the bulbs came on, and boom, you're done. It's much faster. The disadvantage is that you have a single point of possible failure for the entire system.
Different facilities make different choices, I believe both are considered code compliant.
90 minutes run time is the current national standard that all these units are designed for. You can make a system run longer, but it will be a custom system, all the commercial stuff is designed around that 90 minute standard. This time is thought to be enough for people to make their way out of the building safely, and hopefully enough time for medical or repair teams to find their way into the property and fix things.
Common Emergency lighting systems are not designed to allow continued operation of the facility. A backup generator would allow this. I have never seen any kind of emergency light that was motion sensing. Such a thing is certainly possible, but it would either be a custom build or a new item not yet widely in use. The system that came with the building was probably designed specifically so as to satisfy code requirements as cheaply as possible. Nothing forbids you to exceed code.
How can you optimize your existing system? Going beyond 90 minutes is easy. Going into multi-day service would be more involved. The first things to do are:
Get rid of the standard incandescent bulbs and replace them with LEDs where possible. I still use a few icans in places where I need a long throw of light. Incan is still good for throw. Everything else has gone LED. They are a good match to the needs of a 12 volt DC system. Look inside every unit. Figure out how big a battery will physically fit inside the housing and upsize all of them. There is normally a lot of unused space in there. Lead/acid is the norm in emergency batteries. You can get into other chemistries if you are comfortable with them.
Come in after dark one night and do a full system inspection. Shut down power to the facility. Don't just turn off the lights, do a full test. Walk through the entire plant using only the emergency lights. Are there places you could get lost? Places where you can't find the exits? Gaps in coverage? Look for flaws. Often incan lights will be aimed squarely in the eyes of people who are using the system. This means you are walking around in the dark with while a light is shining in your eyes. I consider this poor design.
I don't know who uses your buildings. Statistically, mature women are the most likely to have poor night vision. Consider borrowing some ones grannie, have her walk though with you, ask her what she thinks, listen carefully to what she says. Build a system to her needs and you will have a system that works for 99%+ of the population. Maintenance departments often have young guys in them. They normally have good scotopic vision, know the building well, and will honestly not see problems. :thinking:
(*I am not in fact a lighting engineer, but I'll share with you what I know. I'm on another coast than you and expect regional variations)