meter, or if you dont have a meter a LED will work in a pinch.
there ARE batteries out there that are completly reversed from what we deem to be normal, with a smaller end being negative.
like for example square canned li-ions have the can positive, and a smaller connection sticking out as negative, surprises me everytime , , still.
there are also propriatary and military batteries that are reversed from what we think should be normal convention.
usually the negative is the can, but not at all always, best to check with something that tells you the polarity, or try and find its spec sheet.