Hi, most SiC like that is grown by VPE, which for SiC is often solid sources. Since there are 128 different allotropes of SiC, and only a very few work, I am sure it is quite an exciting process control challenge.
edit - It occured to me that not everyone knows that VPE is vapor phase epitaxy, which more or less means growing crystals by condensing molecules onto a surface in a vacuum.