If I plug a 1 ohm resistor, a 4V cell, and 250mA into LED Pro, I get a Vf of 3.75V. But since 1) XP-G are supposed to be much lower than that, and 2) I have found that I need to add about another 0.3-0.5 ohm to account for the for LEDs own resistance, I then tried 1.5 ohm and get a slightly lower 3.62V Vf which still does not make sense. It should be just under 3V. Assuming nothing is wrong with your LED, I think you may have some contact resistance. Are you just touching the wires to the LED and cells?
Now assuming your cell is partially discharged and plug in 3.6V, I get 3.22V Vf. More reasonable. What is the voltage of the cell you are using?