what is the headlamp going to be made out of? is it plastic, aluminum, those funny things you bite onto for x-rays? lol. at 350mA you dont need much of a heatsink at all, at 750mA, things might get toasty on your forehead. so you might want to have some sort of insulator between the heatsink and your dome. some more info on your design would be helpful. good luck!
EDIT: after thinking about it, i wouldnt run the led at more than 350mA. at that current, youll still be getting just over 100lm from the led which in itself is pretty bright for close up work. 750mA would give you something like 175lm which would just blind you especially if someone had some nice pearly whites.