Don't really understand the reason people want to shorten the life of their batteries by charging them at the high rates....more money than me to burn or maybe just impatient I guess.
Short answer....yes it can be safe to hit a 2500mA AA with 5000mA. Make sure your charger has thermal cutoff/limiting capabilites.
Long answer.....take a look at the Energizer 15 min. charger.....hits an AA cell (from 1 to 4) with a blistering 7.5A.....YES that's 7500mA.
http://data.energizer.com/PDFs/CH15MN.pdf
Talk about shortening the life of a battery.
Actually did some simple cycle tests on a pair of these before getting rid of them. Only tested 3 types of batteries (4 ea.) though (Energizer 2500, I-Power 2300, and Duracell 2300).
Actually had a couple of the I-Power cells (junk IMO) get less then 10 cycles before they died. The other two got less than 25 cycles.
The Energizers (4 of them lasted between 62 and 90 cycles) died pretty quickly too.
The Duracells lasted between 82 and 173 cycles (one cell made it to 173 before it died).
FYI...I consider a cell useless when it can no longer deliver about 70% of its rated capacity.
Granted just simple charging and then using a pair of Lacrosse BC-900's to discharge them all at .5A rate. But, it sure shows that if you want to use the HIGH charge rates, especially rates in the neighborhood of 3C-4C you ARE NOT going to get anywhere near the manufacturers advertised amount of cycles which is usually 500 or 1000.
Even though I don't have the tester to verify it with now, I almost guarantee that if you treat an Eneloop to those rates....you won't get anywhere near the 1000 cycles they advertise.
Besides with the LSD batteries nowadays, I just don't see the NEED to 'BLISTER CHARGE' them (as I call it). Buy a few extra batteries and charge them up ahead of time.