Nice work, the JB weld should work out great. Ive done comparative testing and had stars mounted to heatsinks with JB weld, and it handled reflowing just fine. Cant wait to see the copper inlaid and turned down.
As big and thermally massive as that heatsink is, I'd reflow the LEDs on a stovetop. Add a temperature sensor (the infrared laser ones wont be accurate with bare aluminum!), And if youre using solder paste, apply your paste, heat the whole thing to ~100-115 C, place your LEDs carefully, and turn the stove up and watch closely. Once the solder starts melting, turn off the stove since the temp will keep rising a bit as the heat on the bottom makes it way to the top. let it cool enough for the solder to solidify, then move it to another burner to cool fully (if you have an electric stove. If you have a gas one, I'd imagine its fine just letting it sit where it was)
Dont quench it in water, or cool it very quick, as the ramp down rate is just as important(if not more important) as the ramp up rate.