Whichever one turns it on. There will be no difference.
The 3 way lamp simply has 2 contacts for the base of the bulb. A 3-way bulb simply has 2 contacts at its base, for 2 different filaments inside. There is a 50W filament, and a 100W filament. To get 150W, both filaments are used.
The lamp its self has a swich that supplies power to one, the other, or both of the bottom contacts for the bulb. Since your CFL only has one contact, whatever makes it light up is what you should use. Regardless of which switch position you use, efficiency will be the same - your bulb will be either on at full power or off.