Critical angle of reflection will result in all photons strikeing the surface of your tank at an angle greater than 44deg from perpendicular to reflect rather than penatrate.
This means you will require fairly focused optics to enable the light you create to become useful. I would definately not concern yourself with seeing a series of hotspots in the tank. The surface turbulance and distance to the bottom will definately prevent this from happening. I've tried a couple of LED arrays for aquarium useage a few years ago. For my application which is purely to grow coral, the lack of high power 415nm-430nm LEDs caused the arrays I made with hundreds of the brightest white LEDs I could find to be useless. As far as lighting purely for the purpose of viewing illumination, I did a little test for you with 4 different overdriven CREE flashlights aiming down from the top on 1 half of a 55gal tank in the dark. It was pretty weak and pale, with terrible looking colors on the corals and a sickly unhealthy appearence. Keep in mind that I am used to seeing this tank be hit with 30,000lumens of light in ideal wavelegnths to cause florecence for 11hrs a day, so I am going to be naturally a little funny about what I expect to see.
If I slid all 4 flashlights together and just tried to light the front corner area (about a 6"x6" patch), it appeared bright enough, but the colors just looked like something from the morgue rather than an aquarium. Also, if I lifted the lights just a few inches above the water the lighting pretty much dimmed to nothing in the tank.
A company called Solaris makes LED lighting for aquariums. They use something like 100 luxeon K2's for a typical 55gal tank setup. Draws around 300watts, makes lots of heat, the tank appears dim with poor coral colors and ZERO florecence. The corals all die within a short time due to no wavelegnths of light that support ClorA. The website for the Solaris product is an absolute hysterical sack of lies.
http://www.solarisled.com
If you want some excellent lighting for just viewing purposes, I highly recomend T5HO with proper reflectors. 1 bulb should be more than adquate for just viewing purposes. You will be looking at 54watts @ 95-110lumens/watt to get you ~5000lumens of light into your tank while taking up minimal canopy space and low heat. Bulb phosphors available in any flavor you like, and if you ever decide to step into a planted-tank (highly encouraged) or a reef enviroment, you will allready have a part of your lighting needs ready for the conversion.
Best Wishes,
-Luke