After trying Krytox in a number of applications, I gave up on the stuff entirely. Silicone-based greases simply are not suitable for metal-on-metal contact . . .
You mentioned that you use molybdenum disulphide grease on aluminum. Have you tried it on titanium? (I have heard of MDS being recommended for use on titanium, and was wondering how well it works)
I can see why you would equate Krytox with Silicone, because on aluminum, I find both Krytox and Silicone grease to be equally gritty, and after only a few dozen rotation cycles the grease is completely black with metal particles.
But they aren't equivelent. Real Krytox grease is based on a PFPE synthetic base oil that is very different from the silicone oils used as a base for silicone greases.
Also, the thickener in Krytox Grease is PTFE (Teflon), instead of the finely pulverized silica used as a filler to thicken most silicone greases (silica = finely ground glass or sand, which is why silicone greases have such crappy lubricant properties).
Silicone Grease -
Silicone Base Oil
Silica Thickener
Krytox -
Perfluorinated polyether (PFPE) Base oil
Polytetrafluoroethylene (PTFE) Teflon Thickener
Also, the PFPE base oil used in Dupont Krytox greases comes in various viscosity grades that Dupont arbitrarily numbers from 100 through 107. The Grade 100 base oil has a viscosity of only about 12.4 centistokes (watery thin), and the grade 107 has a viscosity 1535 centistokes (thicker than molasses).
So the lubricant properties (or lack of lubricant properties), in Krytox Grease depends a lot on the exact composition of the grease and the viscosity of the base oil.
The Loctite P/N 29710 Krytox grease I am using is based on Dupont Krytox grade 206 grease which in turn uses a relatively thick grade 106 PFPE base oil with viscosity of about 800-820 centistokes.
Contrary to your experience, I have found that this particular Krytox Grease works really well on stainless steel. VERY smooth operation with no galling, and virtually zero wear.
On titanium, the Loctite 29710 Krytox composition is also quite reasonable, giving me results very similar to what you described for your home-made goop – I.E. very smooth turning operation, but some slight fretting being indicated by gradual blackening of the grease.
It's sad that better results can't be obtained on Titanium, but from the results you described, I guess this is about as good as it gets for titanium (even with a custom grease).
The same Krytox Grease that worked incredibly well on stainless steel, and reasonably well on titanium, causes severe fretting and wear on soft bare aluminum however.
I think the PTFE Teflon particles in the Krytox are the culprit rather than the PFPE base oil. Aluminum is so soft that these small Teflon particles dig into the surface and cause fretting.
As is the case with your home concocted lube, 'Teflon' powder can be added to virtually any type of grease, including those based on silicone oil bases, as well as those based on a traditional hydrocarbon lubricants (and of course the new PFPE based Krytox greases).
With this in mind, I have tried every type of 'Teflon' filled grease I could find, and regardless of the underlying grease type, every single one of them caused fretting and wear on bare aluminum.
This may be why some are having better results on bare aluminum threads with the 50/50 mixed Krytox which, if I understand correctly, has been thinned with a bit more of the PFPE base oil (and therefore has relatively less PTFE)
In any case, I have tried real PFPE Krytox (and several other varieties of generic 'Teflon' PTFE lubricants), plus several types of silicone grease including Nyogel, and all were at least slightly gritty and caused some degree of metal fretting when bare aluminum threads were turned under moderated loads.
The Mobil-1 one grease starts out smoother from day one on aluminum and gets even more buttery smooth the longer it is used.
Also, one last question for fyrstormer -
The Mobil-1 works so well, I am thinking of compounding a nice thick custom grease like yours from the Mobil-1 grease plus some PTFE filler for use on titanium, so I was wondering where you obtained your dry PTFE Teflon power ???