The thing with the most common lithiums most of us are using (ones with PCB protection) is they don't limit voltage, they limit current, or amperage through the cell. I guess it is only safe to pull about twice the rated capacity through the battery at once. So, if you have 1, or 2, or however many batteries stacked together in series, you can still only pull about that same amount of current at once. In addition, the quality of that PCB depends on the maker of the battery.
So, if you are using for instance an ultrafire 18650 rated at 2400 mAh, you could theoriticly draw 4.8 amps at once. A 6 volt bulb * 4.8 amps = 28.8 watts. But, there is more to consider. When we overdrive the bulbs at higher voltages, the effective wattage is also raised, hence the current used is higher as well. In addition, the ultrafire being a "budget" cell odds are the PCB is going to be of lower quality and just not allow that amount of current out. And, the way they work, they seem to limit it even more so from a sudden rush of power going through them, I guess because to the PCB it appears to be a possible short circuit. So, you see people talking about "soft starts" and "NTC's" and such, because they allow a gentler start on the batteries, less voltage to begin with that ramps up. (I don't know exactly how long, but I am thinking less than a second) There are other reason's they work as well, having to do with heat generated and the resistance caused by that heat, thereby actually allowing less current to pass. So you see people talking about a light that may not start on the first click starting after 3 or 4 clicks.
Now in the case of safe lithium cells, the lower voltage ones, there is no protection circuit so you don't have those same problems. But, even with the safe chemistry cells you should still follow the 2C rule for the sake of the battery itself. If you don't, it isn't as dangerous because if a safe chemistry cell vents, it doesn't vent with flames and cause your light to explode and vent poison fumes. But, you still run the risk of venting.
Now in the case of other types of cells, the emolis, and A123's, those rules don't apply. They are perfectly safe to use at very high current levels, I don't know the exact specs, but over 40C in a lot of cases, probably more. In fact, they are designed for it.
So, in the case of very high voltage cells, like the 6x3.7 volt setups you are talking about, you would have to find a bulb that is high voltage, but low wattage, and no examples come to mind for me except HID's. Or, use emoli cells or A123's. Or, you could use 6 cells but in series parralel configuration. So for instance, you have 6 cells, but only 2 of them in series. Now you have doubled your voltage, to 7.4 volts. But, because you have 2 stacks of 3, you have tripled your capacity from 2400 mAh's to 7200 mAh's.
Those are the basics of the batteries, but to get answers from someone who REALLY nows what they are talking about, unlike me, you might be better off posting in the battery forum. As for a light choice, best off finding a combination someone has already made and following there recipe exactly. One light you may enjoy reading about is the mag623. Apparently it is quite a step up from the mag85.