Putting aside that most CFLs, whether warm or cool, have CRIs in the low 80s at best, 2700K to 6500K is a
huge jump. First time I decided to try a 6500K, I thought it looked a little odd at first ( and this is coming from someone who has used cool fluorescents for a long time ). It was MUCH bluer than the usual cool white. That being said, I eventually became used to it. Then again, this CFL had pretty decent CRI. I've seen supposedly 6500K, or daylight, CFLs which not only had awful CRI, but weren't anywhere near 6500K. Some of them looked to be well in excess of 8000K. I don't think anybody can get used to something like that.
And my reactions are similar on the other end of the scale. 2700K, 3000K I just find disgustingly yellow whether it's coming from a CFL or incandescent.

Subjectively, I find the warm CFLs to be worse than incandescents because they often resemble a sodium vapor light in their tint. So for me it's 5000K to 5500K,
high CRI. Generally it's much easier and cheaper to do that with linear tubes as opposed to CFLs, so this is what I use. In fact, regardless of one's preferred preference, linear tubes have always seemed a lot more consistent in their tint between manufacturers than CFLs.
So anyway, yes, there are people that prefer cooler lighting, provided it has decently high CRI. These types of preferences seem to be a cultural and regional type of thing. From what I understand, in Japan 5000K is mostly what people use to light their homes if they have a choice. And in tropical areas cooler lighting is generally preferred. Here in the states it depends. Just looking in houses when I go for walks, it seems both neutral white 3500K and 5000K seem to be catching on now that people are starting to realize they're not limited to incandescent-type light with these things. It's not common by any means, but I suspect if all different options were tried the majority would prefer 3500K or better. Just taking that step up from 2700K to 3500K makes things look 100 times better.