i also thought EDC was something technical, but it's actually the same as for pistols... every-day-carry. i just didn't think people carried flashlight(s) with them every day, until here...
Why not? It is dark at least 50% of the day. Even indoors, there are many low light situations. If you carry a pistol, you need to be able to ID things in low light.
IMO, it is best to learn the fundamental building blocks. With those building blocks, you can put them together to do mod'ing. Crawl, walk, run.
I would go to the library and find some basic books on electricity and circuits and read them. Understand the basics like voltage, current, Ohm's Law, Kirchoff's Law, resistance, capacitance, inductance, and series and parallel circuits. I'd read about LEDs, mechanical switches, LDO regulators, transistors, FETs, diodes, resistors, capacitors, and inductors. I'd learn how to solder. I'd also do a Google search to understand how DC-DC converters (e.g., boost, buck, boost-buck) work. Download and read the LED datasheets from Cree, Seoul, and Luxeon.
Buy a cheap SureFire 6P ("P60") drop-in from DX and take it apart to understand how the components all work together. Get a SureFire 6P or clone host flashlight to do some experiments.
Connect your book learning with the real-world flashlight parts (e.g., the DX drop-in and SureFire 6P host). Begin to understand how the LED and driver work together and how the driver specs relate to the LED's specs.
Get a digital multimeter and start to make some measurements of battery current draw, LED Vf, and LED drive current to further understand how the specs relate to each other. See this
post for some pointers on using a DMM for flashlight-related measurements.
Get a lux meter and start making lux measurements to understand how different specs result in different light output. Build your own
milk carton light box for a homemade, poor man's integrating sphere.
If the driver board for the drop-in specifies some operating voltage range, hook up different battery combinations to see what happens. How does lux change with voltage? How does the battery current draw change with voltage?
Start to do some simple mod'ing that mostly requires mechanical skills like soldering, wiring, sanding, etc. Examples might include swapping driver boards in a DX drop-in, upgrading the LED in a DX drop-in, and building a Maglite mod.
Move up to an intermediate text like Horowitz and Hill's The Art of Electronics. Examine a DX driver board more carefully. Backlight the board and trace the circuitry. Look up all of the components by reading the markings on the various devices and finding their datasheets on the web. Try to understand how the board works.
If you've made it this far, then maybe the next step is to take some machine shop classes and start to make your own stuff.