Hello BVH,
Li-Ion cells are only balanced when fully charged. Once you use them, the balance falls off. Balance is most important when charging cells in series. If the cells are out of balance, you run the risk of overcharging. Secondly, you want to start with a balance charge to get the best performance from your cells.
When I use multiple cells, I first match them on capacity. Then I know that they will all pull together if they start off charged to the same voltage.
Tom